Neutron reflectometry and X ray scattering studies on dopant injection dynamics into correlated nickelates

Abstract

Strongly correlated oxides such as perovskite nickelates present an opportunity for basic research to understand fundamentals of electron interactions in solids as well as potential applications in DoD relevant electronics such as neuromorphic computing and reconfigurable devices. One of the fascinating properties of the nickelate family is the ability to induce temperature independent massive electronic phase transitions (metal insulator transitions with change in resistivity modulation spanning 10 orders of magnitude under ambient conditions) by carrier doping of Ni eg orbitals, also referred to as filling controlled Mott transition. The extent of doping required to cross electronic phase boundaries is of the order of a fraction of an electron to 1 electron - unit cell. Such high carrier densities are required to screen electron correlations that can be in the range of several eV. It is therefore of importance to understand fundamentals of dynamics of injection of dopants into such semiconductors, strain evolution and structural relaxation of the metastable electronic phases formed as dopants are incorporated under electric fields.

Document Details

Document Type
DoD Grant Award
Publication Date
Jan 14, 2022
Source ID
FA95501910351

Entities

People

  • Shriram Ramanathan

Organizations

  • Air Force Office of Scientific Research
  • Purdue University
  • United States Air Force

Tags

Readers

  • Materials Science and Engineering.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene
  • Space