Macromolecular Mechanisms of Biomimetic and Biological Assembly

Abstract

We propose to perform a complementary set of experiments, statistical mechanics based polymer theory, and multiscale molecular modeling on four major areas- (1) New paradigms of structural phase transitions in biomolecular condensates that constitute to a new class of biological organelles without their enclosing membranes, (2) Internal structure and fibrillization in biomolecular con￾densates, (3) Single molecule translocation of intrinsically disordered proteins and their complexes through a single nanopore, and (4) Volume phase transitions of mucus gel and its biomimetics. The conceptual framework to be generated from the proposed research will be general and applicable to a vast set of biomolecular assemblies as well as to make a fundamental understanding of mucus and their mimics. The expected outcome of the proposed research is a fundamental understanding of how biological macromolecules such as intrinsically disordered proteins and RNA organize among themselves and move around in crowded environments. The proposed work is complementary to the ongoing efforts in the current program and many other laboratories worldwide. Our proposal builds on various fundamental concepts from polymer physics, which are pragmatically suited to successfully address the rich phenomenology of biological and biomimetic assemblies. Our work will be conducted in synergistic cooperation between us and several experimental research groups participating in the Natural Materials and Systems Program. In addition, we will continue to pro￾vide support to the program participants with our static and dynamic light scattering expertise as well as theoretical-modeling expertise.

Document Details

Document Type
DoD Grant Award
Publication Date
Mar 07, 2024
Source ID
FA95502310584

Entities

People

  • Murugappan Muthukumar

Organizations

  • Air Force Office of Scientific Research
  • United States Air Force
  • University of Massachusetts

Tags

Readers

  • Defense Technology Research and Development.
  • Molecular and Cellular Biochemistry
  • Nanocomposite Materials Science

Technology Areas

  • Biotechnology