Electrochemical characterization for hybrid battery-propellant processes

Abstract

The project aims to design and study two classes of alkali metal-based battery-propellant hybrid systems- the first based on existing electrochemical systems and the second on a proposed sodium-aluminum catholyte battery with enhanced energy density. After use as secondary rechargeable batteries, the anode of the battery can be melted and mixed with the liquid catholyte, resulting in a monopropellant. Experimental studies will be implemented to gain fundamental insight into the chemistry and physics of such hybrid systems and uncover initiation conditions. Meanwhile, the solid-liquid interfacial behavior of alkali metals will be elucidated and leveraged to suppress dendritic growth and reduce the risk of unintended thermal runaway. As a key enabler of the hybrid systems, a reliable mechanism for in-situ propellant preparation will be uncovered based on controlled melting and mixing of the alkali metal anode with the cathode-catholyte.

Document Details

Document Type
DoD Grant Award
Publication Date
Mar 07, 2024
Source ID
FA95502310640

Entities

People

  • Hai Wang

Organizations

  • Air Force Office of Scientific Research
  • Stanford University
  • United States Air Force

Tags

Readers

  • Economics
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Nanocomposite Materials Science