Phase Transition in 2D Metal Carbides Heterostructures

Abstract

In this three-year project, the contractor will further pursue the research to use MXene as an "integrated, active, and self-recoverable" protector to prevent damage in ICs. Two new material structures based on MXene will be studied : (1) carbon nanotubes (CNTs) growing on the surface of MXenes (CNTs/MXs) in which CNTs act as antennas to enhance the signal coupling and expand the frequency range and (2) 2D transition metal dichalcogenide/metal carbide (TMDCs/MXs) heterostructures in which optoelectrically active metal chalcogenides (for example MoS2) grow epitaxially on metal carbides, forming a novel heterojunction between two phase transition materials (MoS2 can switch between semiconducting 2H and metallic 1T phase). This will be the world#s first study of chalcogenide/carbide phase transition heterostructures with many unforeseen results and potential technical applications. Its impact will be even larger than the #magic angle# between layers of graphene because the compositions of both the top chalcogenide and the bottom carbide can be adjusted freely, yielding endless combinations and possibilities. It can potentially lead to a fast phase transition response and even wider frequency coverage range (expanding from radio frequency to optical), protecting devices from conventional electromagnetic attack and visible/infrared laser based attack. More importantly, it will enable utilizing mature lithium-ion battery technology to study phase transition and equip the existing battery industry for future manufacture of phase transition CDEW devices.

Document Details

Document Type
DoD Grant Award
Publication Date
Jul 24, 2023
Source ID
N000142312569

Entities

People

  • Yue Wu

Organizations

  • Iowa State University
  • Office of Naval Research
  • United States Navy

Tags

Fields of Study

  • Physics

Readers

  • Educational Psychology
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Reinforced Composite Materials

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene