Highly-Transparent Armor Material (SiAlON/SiON) by Hot Isostatic Sintering and Polymer-Derived Ceramic (PDC) Route

Abstract

This proposal is to develop a one kind of lightweight bullet and wear-resistant transparent armormaterial to provide long-term protection for vehicles/aircraft windshields. If successful, we willbe able to reduce the porosity of current transparent bulletproof materials while simultaneouslydecreasing the density to achieve light-weight. Using the polymer-derived ceramic (PDC) routefollowed byhot isostatic sintering, a unique and low-density material which is much lighter thancurrently used material systems will be developed from SiAlON/SiON. This new and effectivetransparent armor will advance the ballistic and wear-resistant capabilities of aircraftwindshieldsand surpass traditional heavy glass laminates.Existing transparent ceramics have a relatively high density (> 3.5 g/cm 3 ) resulting in very heavymaterial products. An ideal transparent ceramic for ballistic protection will have a low densitycorresponding to a light weight and a low thickness. Overall, the ideal transparentarmormaterials should have a combination of all following properties:# Highly optical transparent within the visible and mid-infrared regions of the spectrum# Superior ballistic-resistant performance# Excellent mechanical properties# Lightweight # Low-cost processing methodIn this proposal, a new synthesis method is proposed which uniquely combines the polymer-derived ceramic (PDC) route and the hot isostatic sintering method. The polymer-derivedceramic (PDC) route is a #ceramic through chemistry# that allows synthesizing ceramic materialsin a variety of compositions and shapes, which are difficult to achieve using conventionalapproaches. Different from the lengthy and sophisticated procedures in conventional ceramicssintering method, PDCs are a class of materials directly prepared from the pyrolysis of hyper-crosslinked polymer precursors. Their material formats and complex shapes can be made withthe liquid processing of the polymer precursors. More importantly, the materials# compositionsand microstructures can be tuned with different crosslinking and pyrolysis conditions.Compared with the existing commercial AlON product on the market, the innovation PDC bringsis not only an addition of a component. The benefits are reduced density, less porosity, andimproved optical and mechanical properties that can be designed and adjusted during thefabrication process. The objective of this proposal is to make a highly-transparent armor materialwhich has low density and better resistance to bullet and sand impact.This abstract is publicly releasable.

Document Details

Document Type
DoD Grant Award
Publication Date
Jul 24, 2023
Source ID
N000142312718

Entities

People

  • Chengying Xu

Organizations

  • North Carolina State University
  • Office of Naval Research
  • United States Navy

Tags

Fields of Study

  • Materials science

Readers

  • Powder metallurgy of Titanium alloys.
  • Quantum Dot Semiconductor Device Photonics and Graphene Optoelectronic Materials and THz Physics.
  • Reinforced Composite Materials