AN INVESTIGATION OF ELECTRODE PROCESSES BY MICROSCOPY. PART 2. THE MICROSTRUCTURE OF LEAD DIOXIDE AND SPONGE LEAD PLATES AS INFLUENCED BY DIFFERENT TEMPERATURES, ELECTROLYTE SPECIFIC GRAVITIES, AND CURRENT DENSITIES IN THE FORMING PROCESS

Abstract

Battery plates were formed at specific gravities of electrolyte ranging from 1.05 to 1.45, at temperatures from 4 to 30 deg C, and at current densities from 0.023 to 2.3 amp/sq dm (approximately 0.23 to 23 amp/sq ft). All samples received a total current that was 1/4 of that required for complete formation of a similar plate under the arbitrarily chosen conditions of 30 deg C, 0.23 amp/sq dm current density, and acid specific gravity of 1.050. The plates were impregnated with plastic, sectioned, and polished. The area of formed PbO2 in the positive plate increased as the specific gravity of the acid decreased. The greatest area of PbO2 formation occurred at a current density of 0.023 amp/sq dm. The formed area in the negative plate was greatest at an acid specific gravity of about 1.25. The area of formed material increased as the current density was decreased to 0.23 amp/sq dm, but no increase was observed at lower current density.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1962
Accession Number
AD0272290

Entities

People

  • A. C. Simon
  • Eric Jones

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Antimony
  • Boundaries
  • Chemical Compounds
  • Chemistry
  • Current Density
  • Electric Current
  • Electrodes
  • Government Procurement
  • High Temperature
  • Lead Dioxide
  • Low Temperature
  • Materials
  • Microscopy
  • Military Research
  • Oxides
  • Photographs
  • Specific Gravity

Readers

  • Battery Technology and Engineering
  • Metallurgy
  • Reinforced Composite Materials