SOLID PROPELLANT IGNITION STUDIES: IGNITION OF THE REACTION FIELD ADJACENT TO THE SURFACE OF A SOLID PROPELLANT

Abstract

The object of this research was to elucidate igni tion mechanisms of solid propellants, to identify the component processes, and to lay the basis for a theory of ignition. Experiments were performed in which composite propellant samples and polymeric fuel samples were exposed to high and low speed flows of oxygen containing gases at high temperature and pressure in a shock tunnel. Ignition of either propellant or fuel could not be obtained in high speed flows even in pure oxygen; in addition, no charring or decomposition of the fuel was observed. At low flow speeds, on the other hand, ignition of the composite propellant and the polymeric fuel did occur, and the ignition delay was found to depend on the gas phase oxygen concentration. The non-ignition at high flow speeds indicated that dilution or sweeping away of the gaseous reaction zone inhibited the ignition. Results strongly suggest that the site of ignition is in a gaseous reaction boundary layer adjacent to the surface of the propellant and not on the fuel surface itself.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1963
Accession Number
AD0428602

Entities

People

  • Clarke E. Hermance
  • Reuel Shinnar

Organizations

  • Princeton University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Boundary Layer
  • Chemical Reactants
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Combustion Products
  • Composite Propellants
  • Differential Equations
  • Heat Transfer
  • Ignition
  • Ignition Lag
  • Material Degradation Processes
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Pyrolysis

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Fluid Dynamics.
  • Rocket Propulsion.