HIGH TEMPERATURE PROTECTIVE COATINGS FOR GRAPHITE

Abstract

The evaporation of iridium in the presence of oxygen and water vapor to temperatures of 1300C; the results of studies involving carbon diffusion through iridium; the permeability of iridium, rhodium, ZRO2, HFO2, and THO2 to oxygen at temperatures of 2000C; the coating of graphite with iridium, including the carbon iridium eutectic temperature determination; the reactions of iridium and rhodium with ZRB2, HFB2, ZRC, HFC, and THC2; the kinetics of the carbothermic reduction of ZRO2, HFO2, and THO2 to temperatures in excess of 2000C; the chemical reactions of graphite with ZRB2 and HFB2; and arc plasma tests of iridium-coated graphite. the diffusivity, permeability, and kinetic data are presented in the form of mathematical expressions. A mechanism for the diffusion of oxygen through the refractory oxides based on ion vacancy transport is presented.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1964
Accession Number
AD0608092

Entities

People

  • A. W. Smith
  • E. P. Schram
  • H. F. Volk
  • J. M. Criscione
  • R. A. Mercuri

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Body Weight
  • Ceramic Materials
  • Chemical Analysis
  • Chemical Kinetics
  • Chemical Reactions
  • Chemical Stability
  • Chemical Synthesis
  • Chemistry
  • Crystal Lattices
  • Crystal Structure
  • Heat Energy
  • Materials
  • Materials Laboratories
  • Materials Processing
  • Materials Science
  • Measurement
  • Thermodynamics

Fields of Study

  • Chemistry

Readers

  • Surface Engineering/Surface Coating Technology.