SYNTHESIS OF NEW FLUORINE-CONTAINING NITROSO COMPOUNDS, COPOLYMERS AND TERPOLYMERS
Abstract
The report describes work carried out in the area of nitroso polymers. Two general classes were investigated. These were (1) sulfur- containing nitroso polymers and (2) nitroso polymers containing functional groups. Synthesis of a wide variety of fluorine-containing nitroso compounds and olefins is described, as well as the synthesis of various fluorine- containing intermediates. Nitroso copolymers and terpolymers were prepared containing functional groups such as halogen, ester, double bonds, and methoxy. Properties of selected systems are described. A terpolymer which could be cross-linked by peroxide was prepared using methyl 4-nitrosoperfluorobutyrate as the termonomer. Infrared spectra and NMR analysis of the new monomers and polymers are included.
Document Details
- Document Type
- Technical Report
- Publication Date
- Nov 01, 1967
- Accession Number
- AD0666801
Entities
People
- Calvin D. Padgett
- Eugene C. Stump