Solid Solution Softening (Rhenium Ductilizing Effect and Bubble Strengthening in Tungsten-Rhenium Alloys

Abstract

The effect of carbon additions to tungsten and tungsten-rhenium alloys was determined by anelastic relaxation, stress relaxation and mechanical property studies. Rhenium alone, rather than a combination of rhenium and interstitials, lowers the lattice friction stress (Peierls stress) and is responsible for the ductilizing effect in tungsten. Bubbles were identified at grain boundaries of recrystallized, doped tungsten and tungsten-rhenium alloys from scanning electron microscopy studies of intergranular fracture surfaces. Auger electron spectroscopy demonstrated that these bubbles are coated with potassium which is highly localized at grain boundaries. Varying concentrations of rhenium had no noticeable effect on fracture behavior, bubble size or distribution, or potassium segregation. The bubbles dramatically raise recrystallization temperature and control grain growth texture and are, therefore, responsible for the high temperature creep properties of 'doped' tungsten and tungsten-rhenium alloys.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1973
Accession Number
AD0769343

Entities

People

  • Ronald P. Simpson

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Crystals
  • Electron Microscopy
  • Mass Spectrometry
  • Materials
  • Measurement
  • Mechanical Properties
  • Mechanical Working
  • Solid Solutions
  • Spectra
  • Spectroscopy
  • Stress Strain Relations
  • Stresses
  • Tensile Strength
  • Transition Temperature

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Microelectronics