Electrochemical Demilitarization Of Energetics

Abstract

The key objective of this project was to demonstrate electrochemical treatment of several representative explosive and propellant compounds at the bench-scale. Specific attention was given to determining the overall rates of treatment, delineating the major transformation products of the process, performing carbon and nitrogen mass balances, and assessing the ability lo effectively treat slurried and solid phase explosives and propellants. The technical approach included screening level testing to select the appropriate electrode / electrolyte combination and operational parameters to effectively destroy the target energetic materials (e.g., RDX from Composition B and nitrocellulose). This was be followed by larger bench-scale testing over a longer duration to evaluate treatment effectiveness, generate reaction rates, and determine any electrode fouling or failure possibilities. The proposed technology potential offers DoD a means to address demilitarization waste streams in a manner that does not require the use of dangerous reactive chemicals or environmentally unfriendly processes.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 2018
Accession Number
AD1073452

Entities

People

  • Mark E. Fuller

Tags

Communities of Interest

  • Counter IED
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Aqueous Solutions
  • Chemical Analysis
  • Chemical Engineering
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Demilitarization
  • Department Of Defense
  • Ecology
  • Electrochemical Cells
  • Electrodes
  • Energetic Materials
  • Explosives
  • High Explosives
  • Hydroxyl Radical
  • Material Degradation Processes
  • Materials
  • Materials Laboratories
  • Materials Science
  • Metal Oxides
  • Propellants
  • Solid Phases
  • Therapy

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Environmental Engineering.
  • Rocket Propulsion.