Environmentally Friendly Zirconium Oxide Pretreatment

Abstract

Laboratory corrosion testing has shown zirconium pretreatment to be an environmentally friendly replacement for zinc phosphate treatment on steel and for hexavalent and trivalent chromium on aluminum. To document the performance of zirconium pretreatment in production, demonstrations were conducted at Letterkenny Army Depot in Chambersburg, Pennsylvania, and US Marine Corps Logistics Base Albany in Albany, Georgia. The demonstrations consisted of cleaning parts and panels and treating them with an X-Bond 4000 zirconium treatment followed by painting them with the currently used primer and topcoat. Parts and panels were also prepared using the existent depot technologies for cold rolled steel (zinc phosphate), aluminum (chrome 3+ and chrome 6+), and high hard armor (clean-only). Parts and panels were tested in laboratory-accelerated corrosion chambers, installed on vehicles at US Marine Corps Camp Lejeune, or placed on outdoor exposure at seacoast test facilities. After testing or exposure per the appropriate specification, parts and panels were inspected. Results showed that the zirconium pretreatment under solventborne, waterborne, and powder primers performed better than trivalent chromium and nearly equal to hexavalent chromium on aluminum. On steel, X-Bond 4000 ranged from slightly worse to slightly better than zinc phosphate; it met the performance requirements of TT-C-490. On high hard armor, X-Bond showed improved corrosion inhibition versus grit-blasted only.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 2019
Accession Number
AD1085384

Entities

People

  • Daniel Pope
  • Fred Lafferman
  • Jeff Stalker

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Biomedical
  • Ground and Sea Platforms
  • Human Systems
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Chromium Compounds
  • Coatings
  • Corrosion
  • Corrosion Inhibition
  • Corrosion Resistance
  • Failure Mode And Effect Analysis
  • Ground Vehicles
  • Hydrogen Embrittlement
  • Materials
  • Materials Science
  • Materials Testing
  • Salt Spray Tests
  • Sheet Metal
  • Test And Evaluation
  • Test Methods

Readers

  • Surface Coatings Technology.
  • Surface Engineering/Surface Coating Technology.