Sieve Stack and Laser Diffraction Particle Size Analysis of IMX-104 Low-Order Detonation Particles

Abstract

When an artillery round undergoes a low-order detonation during live-fire training or an unexploded ordnance clearance operation, up to 25 of the rounds energetic contents are scattered over a small, localized area, sometimes less than 100 m2. Training-range fate and transport models require an accurate representation of the particle-size characteristics of the material left behind from low-order detonations. This study investigated using laser diffraction particle size analysis to characterize 26 samples collected from four low-order command-detonated 81 mm mortar bodies filled with IMX-104. The refractive index of IMX-104 was estimated using an iterative recalculation technique on a Horiba LA-960 that yielded 1.845 0.01i. Of the 25 triplicate analyses conducted using this value, 12 passed the USP <429> measurement standard with 9 of the remaining samples found to have had a reduction in particle size during analysis that caused artificially high coefficient of variance values. The cumulative percent of particle sizes determined by laser diffraction and sieve stack differed by 0-21.9% (median = 0.2%7.2%). In addition, the higher resolution results of the laser diffraction particle size analysis, especially for particles smaller than 0.5 mm, make it the preferred method of analysis.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 2020
Accession Number
AD1091644

Entities

People

  • Charles A. Ramsey
  • Katrina M. Burch
  • Matthew F. Bigl
  • Michael R. Walsh
  • Samuel Beal

Organizations

  • Engineer Research and Development Center

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Ammunition
  • Diffraction
  • Energetic Materials
  • Explosives
  • High Explosives
  • Insensitive Explosives
  • Material Degradation Processes
  • Materials
  • Materials Laboratories
  • Materials Testing
  • Measurement
  • Munitions
  • Particle Size
  • Particles
  • Refractive Index
  • Training
  • Unexploded Ammunition

Readers

  • Aerosol Science/Aerosol Physics
  • Agricultural Chemistry/Soil Science
  • Nanofabrication and Microfabrication.

Technology Areas

  • Directed Energy