A Novel Approach to Thermoelectric Material Fabrication Using Additive Manufacturing

Abstract

Recently there has been increased interest in developing thermoelectric materials with additive manufacturing (AM) techniques. Thermoelectric material scan capture waste heat and generate electricity. These materials have not seen widespread application for several reasons including: inefficient material properties, and fabrication difficulties. AM thermoelectric materials have demonstrated lower thermal conductivities, which can be a hallmark of a more efficient thermoelectric device. AM can also be used to create difficult geometries geometries unobtainable with standard fabrication techniques. The goal of this work was to develop and characterize an AM fabrication method capable of creating dimensionally accurate thermoelectric materials. N-type bismuth telluride (BiTe) was chosen as the base material due to availability and effectiveness as a room temperature thermoelectric. Initial methods of fabrication used a Form labs Form2 Printer and a doped resin. Image analysis was done to verify the doping percentage. However, thermoelectric characterization showed that these samples did not exhibit a Seebeck effect and were therefore not functional thermoelectric materials. Due to the printers limitations with doped resin, a method labeled bulk curing in plastic AM molds was devised. The maximum concentration achieved was 80wt BiTeSe. Once sintered, the samples exhibited a measurable thermoelectric effect. Mechanically the materials demonstrated non-homogeneous hardness characteristics.

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Document Details

Document Type
Technical Report
Publication Date
May 16, 2022
Accession Number
AD1171861

Entities

People

  • James J. Potticary

Organizations

  • United States Naval Academy

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Engineered Resilient Systems

DTIC Thesaurus Topics

  • Additive Manufacturing
  • Ceramic Materials
  • Fabrication
  • Fused Deposition Modeling
  • Grain Size
  • Heat Energy
  • Manufacturing
  • Manufacturing Engineering
  • Materials
  • Materials Processing
  • Materials Science
  • Materials Testing
  • Measurement
  • Mechanical Properties
  • Microscopy
  • Seebeck Effect
  • Selective Laser Sintering
  • Three Dimensional
  • United States Naval Academy
  • Voltage

Fields of Study

  • Materials science

Readers

  • Reinforced Composite Materials
  • Solar Photovoltaics and Thermoelectric Devices.