Generating Formate from CO2 On-Site

Abstract

Major Goals: The main objective of this proposal was to build an electrochemical device that can convert waste carbon dioxide from point sources on outposts and bases into potassium formate (K-Formate). K-Formate is an environmentally friendly deicing agent with low corrosivity and suitable for roadway and runway deicing. It has already been formulated to meet the AMS 1435 standard for runways. BASF has tested its version of K-Formate with additives at airports, including Denver International Airport, while Eastman has tested a similar product inEurope. Presently K-Formate is manufactured at chemical plants in Europe or Asia and is then shipped around the world for sale. Production and delivery costs could be substantially reduced by using inexpensive and/or waste materials (renewable electricity, carbon dioxide, sea salt) and synthesizing the chemical in reactors on-site. One of the Armys modernization priorities is to lower supply chain costs. By relieving pressures on the supply chain, the chemical stockpiles can also be reduced, reducing costs and potentially saving lives. In the proposed work, we designed and developed a small unit to produce formic acid. We ran the device for 500 hours producing enough formic acid to yield of K-Formate using KOH neutralization, and delivered 5 lbs of the KFormate solution to the ARO (Army).

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Document Details

Document Type
Technical Report
Publication Date
Mar 24, 2021
Accession Number
AD1187969

Entities

People

  • Jerry Kaczur

Organizations

  • Dioxide Materials

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Carbon Dioxide
  • Cost Estimates
  • Costs
  • Current Density
  • Economic Models
  • Efficiency
  • Energy Consumption
  • Failure Mode And Effect Analysis
  • Formates
  • Formic Acid
  • Ion Exchange
  • Ion Exchange Resins
  • Materials
  • Models
  • Production
  • Production Models
  • Standards
  • Supply Chain

Readers

  • Aviation Safety and Air Traffic Management
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Environmental Engineering.