Laser-Interference Surface Preparation for Enhanced Coating Adhesion and Adhesive Joining of Multi-Materials

Abstract

This report investigates a laser-interference surface treatment as a non-contact, i.e., without major solid/liquid medium application or abrasion, and non-chemical surface preparation method for aerospace coating systems. It was proposed to use the laser-interference technique to structure surfaces of Al and/or Ti, creating "rough" surfaces with pre-engineered series of ridges and valleys at submicron scale. The science goal of this study was to develop an understanding of the surface microstructure, topology, and physical mechanisms that would improve adhesion and corrosion protection of Al2024-T3. Microstructure analysis indicates that the laser-interference structuring (LIS) was found to reduce the formation of CuMn-rich precipitates in Al 2024-T3 over a 500-800 nm depth from top surface. The X-cut and cross-hatch coating adhesion ratings indicate that the LIS specimens meet the performance requirements in the coating adhesion specifications by having a higher or identical ranking to those specimens prepared with current state-of-the-art chemical conversion or sulfuric acid anodizing. After the ASTM B117 corrosion exposure, it was found that the laser processed specimens exhibited only few blisters. It was found that the corrosion damage was minimized at a laser rastering speed of 4 mm/s, for which only 33% of specimens developed very minor corrosion damage. The ASTM D1654 creepage ratings, used to evaluate corrosion damage along the scribe lines, were found to be at least nine for all coated panels. These results indicate that the laser-interference technique with the additional acetone wiping has the potential to be further developed as a minor chemical surface preparation technique for chromate-containing epoxy primers coatings.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 2021
Accession Number
AD1191465

Entities

People

  • Adrian S Sabau
  • Donovan Leonard
  • Harry Iii Meyer
  • Jianlin Li
  • Jiheon Jun

Organizations

  • Oak Ridge National Laboratory

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aluminum Alloys
  • Chemical Analysis
  • Chemical Synthesis
  • Chemistry
  • Corrosion
  • Corrosion Inhibition
  • Corrosion Resistance
  • Laser Beams
  • Material Degradation Processes
  • Materials
  • Materials Engineering
  • Materials Processing
  • Materials Science
  • Optical Properties
  • Optics
  • Surface Chemistry
  • Surface Finishing
  • Surface Properties
  • Surface Roughness

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Nanoscale Plasmonic Nanotechnology
  • Polymer Science and Engineering.

Technology Areas

  • Directed Energy
  • Space