Aqueous Film Forming Foams Based on Biodegradable Natural Surfactants and Additives

Abstract

The objective of this Limited Scope Research work is the development of non-fluorinated, biodegradable bio-derived film-forming composite formulations based on parts of plantain that can be used instead of toxic and bio-persistent polyfluorinated firefighting foams. The aim was to develop firefighting products that meet the performance requirements specified in MIL-F-24385F, which are also environmentally compatible and non-toxic. The banana sap containing a mixture of organic chemicals did not exhibit pool fire quenching properties. The banana peel powders contained potassium as the major inorganic content and, as such, did not contribute to the firefighting. Water-soluble cellulose derived from banana peel powder was tested as a foam stabilizing additive to siloxane and hydrocarbon surfactants in the PFAS-free firefighting foam formulations. The banana peel-derived cellulose demonstrated low viscosity than commercial polysaccharide additives and excellent firefighting capability when mixed with conventional surfactants. The banana-cellulose mixed surfactant formulations could potentially replace AFFF formulations with scaled-up production of banana-cellulose powders and optimization of the PFAS-free formulations towards meeting the Mil-Spec standard.

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Document Details

Document Type
Technical Report
Publication Date
Apr 15, 2022
Accession Number
AD1191505

Entities

People

  • Kris Rangan
  • Tirumalai Sudarshan

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Alcohols
  • Anhydrides
  • Biological Products
  • Cellulose
  • Cellulose Fibers
  • Composite Materials
  • Congress
  • Department Of Defense
  • Elements
  • Films
  • Flame Retardants
  • Fuels
  • Inorganic Chemicals
  • Law
  • Materials Laboratories
  • Mixtures
  • Organic Compounds
  • Plastics
  • Polymeric Films
  • Polymers
  • Sodium Hydroxide
  • Standards
  • Surface Tension
  • Vitamin E

Readers

  • Fire Suppression Systems Design.
  • Petroleum Engineering
  • Polymer Science and Engineering.