Enhancing Dispersion of Carbon Nanotubes within Metal Matrix Composites

Abstract

The dispersion of carbon nanotubes (CNTs) in an aluminum (Al) metal matrix composite (MMC) was explored in this thesis. CNTs have demonstrated strong and lightweight properties, making them a promising candidate for composite development in maritime, aeronautical, and aerospace industries. Different methods for combining CNTs with Al powder were tested including high energy ball milling (HEBM), cryomilling, and wet chemistry methods. The powders were analyzed via scanning electron microscopy (SEM) to determine which method maximizes CNT dispersion while minimizing breakage or agglomerations. It was found that wet chemistry ultrasonication in acetone created a powder composite with the smallest CNT agglomerations. The HEBM at 1 to 2 ball to powder ratio (BPR) was the next best dispersion technique. The powders that demonstrate adequate dispersion were selected for cold spray onto 6061 aluminum alloy substrate bars. Cold spray has the distinct advantage of deformation at low temperatures avoiding the heat induced defects inherent in welding. Composite powders of 1, 2, and 3 volume percent CNT for the HEBM and the acetone dispersion techniques were mixed and cold sprayed. The cold-sprayed formulations were tested for corrosion and wear resistance. The deposition efficiency of these coatings, especially for the ultrasonicated powders, was extremely low and requires further parameter optimization to obtain usable mechanical performance results.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2023
Accession Number
AD1213629

Entities

People

  • Margaret C Ruud

Organizations

  • Naval Postgraduate School

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Carbon Nanotubes
  • Chemical Synthesis
  • Chemistry
  • Composite Materials
  • Department Of Defense
  • Dispersions
  • Electron Microscopy
  • Graphene
  • Graphitic Materials
  • Material Degradation Processes
  • Materials
  • Materials Processing
  • Materials Science
  • Mechanical Properties
  • Mechanical Working
  • Metal Matrix Composites
  • Microscopy
  • Modulus Of Elasticity
  • Polymer Matrix Composites
  • Thermal Spraying

Fields of Study

  • Materials science

Readers

  • Nanocomposite Materials Science
  • Powder metallurgy of Titanium alloys.
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Microelectronics
  • Space