Oscillatory Indirect Interaction Between Adsorbed Atoms.
Abstract
The oscillatory part of the indirect interaction between two adatoms on a metal surface, separated by a large distance R, is examined for the jellium as well as for the tight-binding model. The asymptotic form of the interaction is derived from the singularity of its Fourier transfer at wave number of q = 2k(F). For a substrate with a spherical Fermi surface, the interaction energy is proportional to cos 2k(F)r)/(R to the 5-th power). For substrates with a partially filled surface band, the interaction energy falls off much more slowly. Under simple assumptions, the interaction behaves as cos(2K(F)R)/R squared. Comparisons are made with the numerical calculations by Einstein and Schrieffer. The experimental results of Tsong on Re atoms adsorbed on W using field-ion microscopy are also discussed.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 01, 1977
- Accession Number
- ADA042376
Entities
People
- Kin-Hing Lau
- Walter Kohn
Organizations
- University of California, San Diego