Infrared Optical Properties of Solid Mixtures of Molecular Species at 20 K

Abstract

Infrared transmittance spectra were measured by a Fourier transform spectrometer for 20 K cryofilms of homogeneous mixtures of N2, Ar, NH3, CO, CO2, and H2O molecules. Such cryofilms may contaminate cryogenic optical surfaces of spacecraft or aircraft. The films, cryopumped onto a 20 K germanium substrate, varied from 0.24 to 13 micrometers thick. The spectral domain ranged from 500 to 3700/cm. For all films, the complex refractive index (n = n + iK) was determined at each wavenumber by fitting the experimental behavior of the transmittance with film thickness to a lamellate model of the film and substrate. The model accounts for beam reflection losses as well as attenuation caused by passing the beam through the film and substrate materials. A Kramers-Kronig (KK) technique for obtaining the n values is compared with the thin-film determination of n.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1981
Accession Number
ADA094214

Entities

People

  • Bobby E. Wood
  • J. A. Roux
  • K. F. Palmer

Organizations

  • Arnold Engineering Development Complex

Tags

Communities of Interest

  • Advanced Electronics
  • Air Platforms
  • C4I

DTIC Thesaurus Topics

  • Absorption
  • Air Force
  • Chemistry
  • Computations
  • Distortion
  • Materials
  • Materials Science
  • Measurement
  • Optical Properties
  • Physical Properties
  • Quartz Crystal Microbalances
  • Refraction
  • Refractive Index
  • Scattering
  • Spectroscopy
  • Thick Films
  • Thin Films

Fields of Study

  • Physics

Readers

  • Spectroscopy.
  • Surface Engineering/Surface Coating Technology.

Technology Areas

  • Space