Composite Pyroelectric Materials

Abstract

New types of composite materials and various single crystal materials were studied for pyroelectric applications. The pyroelectric figure of merit (p/ K) was measured using a fully automated direct (Byre-Roundy) and Chynoweth system built during the past year. Composites of ferroelectric oxides such as PZT, boracites, lead germanate with the polymer spurrs were fabricated. In PZT- Spurrs composites, the pyroelectric figure of merit p/K was improved by a factor of 7 over that of solid PZT. Boracites:Spurrs and Lead Germanate:Spurrs composites possess p/K values equivalent to the figure of merit of their respective single crystalline forms. A new technique was developed to fabricate oriented glass-ceramic pyroelectric targets using large temperature gradients across the glass disk. Pyroelectric figures of merit for recrystallized Li2Si2O5, Ba2Ge2TiO8 and Ba2Si2TiO8 were up to 60% of the single crystal values. Single crystals of antimony sulfur iodide, lithium silicate, lithium germanate, and resorcinol were studied for their potential applications in the pyroelectric devices. SbSI family members have some potentials as oblique-cut targets at low temperatures.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1980
Accession Number
ADA098996

Entities

People

  • A. S. Bhalla
  • Robert E. Newnham

Organizations

  • Pennsylvania State University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Composite Materials
  • Crystal Structure
  • Crystallization
  • Crystals
  • Dielectric Permittivity
  • Dielectric Properties
  • Electromagnetic Fields
  • Materials
  • Materials Processing
  • Materials Science
  • Measurement
  • Phase Transformations
  • Piezoceramics
  • Temperature Gradients
  • Transition Temperature

Readers

  • Materials Science and Engineering.
  • Organic Chemistry