Characterization of Pollutants at Holston Army Ammunition Plant

Abstract

The development of reliable analytical methodologies for the identification and qualification of explosives and related pollutants in effluent wastewaters and the results obtained by direct instrumental techniques are described. This study included the evaluation of sample degradation during storage, a comparison of solvent extraction and other concentration techniques, and the development of an isotope dilution technique. The major pollutants quantified are, in the order of decreasing abundance, 1,3,5-trinintro-1,2,5- triazacyclohexane (RDX), 1-Acetyl-3,5,7-trinitro-1,3,5,7-tetraazacycooctane (SEX), 1,3,5,7-tetranitro-1,3,5,7-tetrazacyclooctane (HMX), and 2,4,6- trinitrotoluene (alpha-TNT) for the organic compounds, and sulfate, chloride, sodium, potassium, and ammonium ions for the inorganic ions. The concentrations of copper, cadmium, and chromium were found to be, respectively, about 10, 1, and 0.02 ppb.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1981
Accession Number
ADA107340

Entities

People

  • C. Campbell
  • T. H. Chen
  • W. J. Fisco

Organizations

  • United States Army Armament Research, Development and Engineering Center

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkanes
  • Chlorides
  • Degradation
  • Dilution
  • Energetic Materials
  • Explosives
  • Extraction
  • Flow Rate
  • Liquid Chromatography
  • Mass Spectra
  • Materials Testing
  • Measurement
  • Molecular Weight
  • Organic Compounds
  • Separators
  • Solvent Extraction
  • Spectra

Fields of Study

  • Environmental science

Readers

  • Agricultural Chemistry/Soil Science
  • Environmental Engineering
  • Systems Analysis and Design