Hydrogen-Free Electrodeposition of Cadmium Coatings on High-Strength Steel for Corrosion Protection

Abstract

A raw method of electroplating cadmium onto high-strength steel has been developed at Argonne National Laboratory. The method has three aspects: (1) high-rate electrodeposition by pulsed currents in a flow cell that uses a flowing electrolyte; (2) an optimized pulse-nucleation step, followed by pulse or DC current growth of the electrodeposit; and (3) the use of aqueous fluoborate electrolyte. The electrolyte flow/pulse-plating method with aqueous fluoborate provides a unique approach for high-speed, hydrogen-free cadmium plating of steel in engineering shapes and sizes. A second method, which is based on electrodeposition from a molten salt, has also been investigated and shows promise as yet another hydrogen-free cadmium-plating technique. Keywords: Electrodeposition, Pulse current, High current density pulse-nucleation, Hydrogen-free cadmium, Flow call fluoborate, Molten salt.

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Document Details

Document Type
Technical Report
Publication Date
Feb 29, 1988
Accession Number
ADA197711

Entities

People

  • H. Shimotake
  • Rohan Varma
  • T. Hoeller

Organizations

  • Argonne National Laboratory

Tags

Communities of Interest

  • Cyber
  • Energy and Power Technologies
  • Ground and Sea Platforms
  • Space

DTIC Thesaurus Topics

  • Boundary Layer
  • Chemistry
  • Coatings
  • Computer Programs
  • Computers
  • Crystal Growth
  • Crystal Structure
  • Crystals
  • Diffraction
  • Electrochemical Cells
  • Electroplating
  • Hydrogen
  • Hydrogen Embrittlement
  • Hydroxides
  • Material Degradation Processes
  • Materials
  • Measurement

Fields of Study

  • Materials science

Readers

  • Surface Engineering/Surface Coating Technology.