Synthesis and Charge Transport Properties of Polymers Derived from Oxidation of 1-H-1'(6-pyrrol-1-yl)-hexyl-4,4'-bipyridinium Bis-hexafluorophosphate and Demonstration of a pH Sensitive Microelectrochemical Transistor Derived from the Redox Properties of a Conventional Redox Center.

Abstract

This article describes the synthesis and electrochemical properties of redox polymers, having a poly-pyrrole backbone and viologen subunits, derived from oxidative electropolymerization of 1-methyl-1'-(6-pyrrol-1-yl)-hexyl-4,4'-bipyridinium, (P-V-Me2+), and 1-H1'-(6-pyrrol-1-y1)-hexyl-4,4'-bipyridinium, (P-V-H2+). Keywords: Pyrroles, Pyridinium. (MJM)

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Document Details

Document Type
Technical Report
Publication Date
Aug 15, 1988
Accession Number
ADA198122

Entities

People

  • Ching-fong Shu
  • Mark S. Wrighton

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Aqueous Solutions
  • Chemical Synthesis
  • Chemistry
  • Conductive Polymers
  • Electrochemistry
  • Electrodes
  • Films
  • Materials
  • Military Research
  • Molecules
  • Polymeric Films
  • Polymers
  • Semiconductor Devices
  • Steady State
  • Transport Properties

Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Molecular and Cellular Biochemistry