Materials Processing Diamond: Etching, Doping by Ion Implantation and Contact Formation

Abstract

We have doped natural diamond with B or P ion implantation at liquid nitrogen temperature. Ions of C were implanted prior to the dopant implants, in order to enhance the vacancy concentration in the diamond, thereby increasing the likelihood that the dopant atoms would occupy substitutional lattice sites, and thus be electrically active. Various post-implantation annealing methods were employed to reduce the residual damage in the crystals. Type IIa diamond crystals were implanted with boron ions with or without prior carbon ion implantation. The samples were kept at liquid nitrogen temperature during both implantation steps. A strong near-edge optical absorption band appeared after implantation, and partially recovered during annealing at 800 C. For the highest B implantation fluence, optical absorption peaks at 2800 to 3000 reciprocal centimeters were observed that were in the same vicinity as the absorption peaks attributed to substitutional boron atoms in natural p-type diamond.

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Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1988
Accession Number
ADA202380

Entities

People

  • Wei-kan Chu

Organizations

  • University of North Carolina at Chapel Hill

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Absorption
  • Chemical Vapor Deposition
  • Electrical Measurement
  • Electron Microscopes
  • Heat Of Activation
  • Heat Of Formation
  • Heat Treatment
  • Ion Implantation
  • Low Temperature
  • Materials
  • Materials Processing
  • Measurement
  • Microscopes
  • Microscopy
  • Optical Absorption
  • Refractory Metals
  • Scattering

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Thin Film Deposition Science.