Low Loss Substrates for Microwave Applications and Sol-Gel Processing of Superconductors.

Abstract

This document is a final technical report of the research program entitled 'Low Loss Substrates for Microwave Applications and Sol-Gel Processing of Superconductors. Systematic studies on low K oxide substrate materials suitable for epitaxial deposition of high Tc superconducting (HTSC) yttrium barium cuprate (YBCO) films and their microwave applications have been extended to oxide materials with magnetoplumbite structure, such as LaMgAl11O19, NdGaMgAl10O19, CaGa6Al6O19, and CaGa12O19. The unique capabilities of a laser heated pedestal growth (LHPG) system have been utilized for test growth of candidate materials in single crystal fiber form to determine structure, thermal, and dielectric properties and to make positive identification of twin free systems. Dielectric properties, thermal expansion coefficients, melting temperatures and growth feasibility were tested. Through successful collaboration thorough tests on the compatibility of the SAT films as buffer layer in MgO/YBCO system have been performed. Excellent epitaxial YBCO films with Jc of 10(exp 6) A/cu cm were reproducibly obtained. Mechanisms relating the bonding nature and the order disorder in complex perovskite niobates and tantalates that governing the characteristics of their dielectric properties were studied through collaboration with the microprobe Raman spectroscopy groups. Work on the Shannon ion polarizability model for predicting dielectric permittivity in solids is being continued. Newly compiled normalized ion polarizabilities which take into consideration apparent bonding strengths improve the predictive capability considerably.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1996
Accession Number
ADA321849

Entities

People

  • Amar S. Bhalla
  • Leslie Eric Cross
  • Rustum Roy

Organizations

  • Pennsylvania State University

Tags

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Crystallography
  • Crystals
  • Dielectric Permittivity
  • Dielectric Properties
  • Dielectrics
  • Diffraction
  • Materials
  • Materials Processing
  • Materials Science
  • Measurement
  • Raman Spectroscopy
  • Single Crystals
  • Spectroscopy
  • X-Ray Diffraction

Fields of Study

  • Materials science
  • Physics

Readers

  • Materials Science and Engineering.
  • Superconducting Magnet Technology
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Pulsed-Laser Deposition