Synthesis of Tetraazacrown Ethers Containing Two 8-Hydroxyquinoline Side Arms

Abstract

Four new tetraazacrown ethers containing two 8-hydroxyquinoline side arms were prepared first by reductive amination of 8-acetoxyquinolin-2-carbaldehyde with the appropriate tetraazacrown ether containing two microring NH functions. The resulting bis(8-acetoxy-1-quinolinylmethyl)-substituted tetraazacrown ethers were treated with 10% aqueous KOH followed by acid to form the N,N'-bis(8-hydroxy-2-quinolinylmethyl substituted tetraazacrown ethers.

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Document Details

Document Type
Technical Report
Publication Date
Apr 06, 1999
Accession Number
ADA361693

Entities

People

  • Jerald S. Bradshaw
  • Krzysztof E. Krakowiak
  • Paul B. Savage
  • Reed Izatt
  • Zhaoxia Yang

Organizations

  • Brigham Young University

Tags

DTIC Thesaurus Topics

  • Alkanes
  • Biochemistry
  • Chemical Synthesis
  • Chemistry
  • Chromatography
  • Crown Ethers
  • Crystal Structure
  • Ethers
  • Imines
  • Information Operations
  • Macrocyclic Compounds
  • Metals
  • Military Research
  • Organic Chemistry
  • Post-Transition Metals
  • Reducing Agents
  • Universities

Fields of Study

  • Chemistry

Readers

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