Profiling Jet Fuel on Neurotoxic Components With Comprehensive Two-Dimensional GC

Abstract

Exposure to jet-propulsion fuel 8 (JP-8) is probably the most occurring chemical exposure within the military. The discussion on the possible adverse health effects of such an exposure is ongoing. Methodology is needed to identify and quantify low concentrations of potentially toxic components in the complex JP-8 matrix. Comprehensive GC (GCxGC), in which continuous two-dimensional separation occurs, was shown to be highly suitable for this purpose. =In combination with time-of-flight mass-spectrometry up to 3,500 components in JP-8 could be chromatographically resolved, in most cases identified and (semi-)quantified. Differences in composition between JP-8 from various sources and with various ages were demonstrated. This technology was used to establish the evaporation profiles at -10 and 20 C of 20 components that are considered to be potentially neurotoxic. Rough estimates of the external exposures of personnel were made from these evaporation profiles as well as preliminary toxicological evaluations.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Nov 01, 2007
Accession Number
ADA475160

Entities

People

  • Henk C. Trap

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Air Force
  • Aircrafts
  • Alkanes
  • Alkenes
  • Aromatic Hydrocarbons
  • Chemical Warfare Agents
  • Cyclic Hydrocarbons
  • Health Services
  • Hydrocarbon Fuels
  • Jet Engine Fuels
  • Jet Propulsion
  • Mass Spectrometers
  • Mass Spectrometry
  • Medical Personnel
  • Pattern Recognition
  • Spectrometry
  • Two Dimensional

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry
  • Petroleum Engineering
  • Toxicology/Environmental Toxicology