MURI Real Time, Explosive Specific Chemical Sensors: Spectroscopic and Time-Domain Detection of Trace Explosives in Condensed and Vapor Phases

Abstract

Under this MURI, research into the use of terahertz spectroscopy, femtosecond laser-induced breakdown spectroscopy, infrared spectroscopy, laser ionization-mass spectrometry and cavity ring-down spectroscopy for explosives detection was pursued. Fundamental studies have been completed that contribute to our understanding of explosives and how they behave when being sensed using the techniques selected for study. The highest level conclusion reached in this program is that all of the techniques have the ability to detect explosives in the environment - the critical issues that are still unresolved are the ultimate selectivities and sensitivities of these techniques. At this time, it is clear that the current sensitivities of terahertz techniques allow for detection of column/surface concentrations of approximately 10 micro-g/cm2, laser induced breakdown spectroscopy can detect at levels below 10 micro-g/cm2, and cavity ring-down spectroscopy can detect vapor phase concentrations below 1 ppb. While these levels of detection have been demonstrated through work in the MURI, more important results have been obtained that point in critical directions for the success of sensing schemes that might be pursued in the future.

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Document Details

Document Type
Technical Report
Publication Date
Mar 27, 2008
Accession Number
ADA482356

Entities

People

  • James B. Spicer

Organizations

  • Johns Hopkins University

Tags

Communities of Interest

  • Advanced Electronics
  • C4I
  • Counter IED
  • Sensors

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Detection
  • Detectors
  • Explosives
  • Femtosecond Lasers
  • Laser Applications
  • Laser Induced Fluorescence
  • Laser-Based Detection
  • Lasers
  • Mass Spectrometry
  • Optical Properties
  • Scattering
  • Spectra
  • Spectrometry
  • Spectroscopy
  • Terahertz Radiation

Fields of Study

  • Physics

Readers

  • Analytical Chemistry
  • Optical Physics and Photonics.
  • Research Science/Academic Research

Technology Areas

  • Directed Energy