Thermodynamic Calculations Predicting MgO Saturated EAF Slag for Use in EAF Steel Production

Abstract

Foamy slags are widely used in EAF steel production because the use of these slags result in energy savings, productivity improvements, and enhanced refractory service life. Foamy slag requires the control of slag viscosity to sustain gas bubbles during processing. This is accomplished through the precipitation of magnesium wustite particles in the slag at the operating temperature. A thermodynamic program, Factsage (trademark), was utilized to study the quaternary oxide system of MgO-CaO-FeO-SiO2, to predict the dual (saturated with CaO and MgO) and MgO saturated EAF slag chemistry under different oxygen partial pressures temperatures, and slag basicity. These predictions indicate a linear relationship between oxide components and slag basicity, from which an accurate prediction of the optimum slag chemistry can be made. The results of the Factsage (trademark) models will be compared to models developed by other researchers and experimental data.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 2009
Accession Number
ADA538351

Entities

People

  • Art Petty
  • Hugh Thomas
  • James M Bennett
  • Kyei-sing Kwong
  • Rick Krabbe

Organizations

  • United States Department of Energy

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Carbon Monoxide
  • Chemistry
  • Data Analysis
  • Dielectric Gases
  • Elements
  • Magnesium
  • Magnesium Compounds
  • Materials
  • Materials Science
  • Metals
  • Oxides
  • Oxygen
  • Partial Pressure
  • Phase Diagrams
  • Piezoelectric Crystals
  • Precipitation
  • Standards

Fields of Study

  • Materials science

Readers

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  • Materials Science and Engineering.
  • Metallurgy