Development of Detailed and Reduced Kinetics Mechanisms for Surrogates of Petroleum-Derived and Synthetic Jet Fuels

Abstract

The oxidation and pyrolysis of n-alkanes and n-alkenes up to n-C12H26 as well as selected cycloalkanes, iso-alkanes, aromatics, and jet fuels were studied experimentally behind reflected shock waves, in flow reactors, and in laminar flames. The measurements included ignition delays and species time evolutions in shock tubes, species profiles in flow reactors, and propagation speeds and ignition/extinction limits of laminar flames. The fundamental kinetic data were used to develop and validate a detailed reaction model for the combustion of n-alkanes up to n-C12H26 as well as cyclohexane and mono-alkylated cyclohexane fuels. The resulting JetSurF model is documented online at http://melchior.usc.edu/JetSurF. Validation tests show that the JetSurF (versions 1.0 and 2.0) is capable of predicting the majority of the experimental data satisfactorily. This was a collaborative three-year research effort between the following universities and investigators: (1) University of Southern California: F.N. Egolfopoulos (PI), H. Wang (co-PI); (2) Drexel University: N.P. Cernansky (co-PI), D.L. Miller (co-PI); (3) Princeton University: C.K. Law (co-PI); (4) Stanford University: C.T. Bowman (co-PI), R.K. Hanson (co-PI), H. Pitsch (co-PI).

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Document Details

Document Type
Technical Report
Publication Date
Feb 28, 2011
Accession Number
ADA547635

Entities

People

  • Fokion N. Egolfopoulos

Organizations

  • University of Southern California

Tags

Communities of Interest

  • Energy and Power Technologies
  • Ground and Sea Platforms
  • Materials and Manufacturing Processes
  • Sensors
  • Space

DTIC Thesaurus Topics

  • Alkanes
  • Alkenes
  • Chemical Kinetics
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Cyclic Hydrocarbons
  • Detectors
  • Hydrocarbon Fuels
  • Ignition Lag
  • Jet Engine Fuels
  • Kinetics
  • Lasers
  • Organic Chemistry

Readers

  • Combustion science or combustion engineering.
  • Organic Chemistry
  • Research Science/Academic Research