Elucidation of the Dynamics for Hot-Spot Initiation at Nonuniform Interfaces of Highly Shocked Materials

Abstract

The fundamental processes in shock-induced instabilities of materials remain obscure, particularly for detonation of energetic materials. We simulated these processes at the atomic scale on a realistic model of a polymer-bonded explosive (3,695,375 atoms/cell) and observed that a hot spot forms at the nonuniform interface, arising from shear relaxation that results in shear along the interface that leads to a large temperature increase that persists long after the shock front has passed the interface. For energetic materials this temperature increase is coupled to chemical reactions that lead to detonation. We show that decreasing the density of the binder eliminates the hot spot.

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Document Details

Document Type
Technical Report
Publication Date
Dec 07, 2011
Accession Number
ADA554817

Entities

People

  • Andres Jaramillo-botero
  • Mario Blanco
  • Qi An
  • Sergey V. Zybin
  • Sheng-nian Luo
  • William Andrew Goddard III

Organizations

  • California Institute of Technology

Tags

Communities of Interest

  • Counter IED
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkenes
  • Chemical Reactions
  • Chemistry
  • Dynamics
  • Energetic Materials
  • Explosives
  • High Density
  • Hot Spots
  • Hydroxyl Terminated Polybutadiene
  • Materials
  • Materials Laboratories
  • Materials Science
  • Molecular Dynamics
  • Plastic Bonded Explosives
  • Quantum Mechanics
  • Rdx
  • Shock Waves

Fields of Study

  • Physics

Readers

  • Combustion Dynamics and Shock Wave Physics.
  • Rocket Propulsion.
  • Theoretical Analysis.