Cost and Performance Report: Low-Hazardous Air Pollutant (HAP)/Volatile Organic Compound (VOC)-Compliant Resins for Military Applications

Abstract

Liquid resins used for molding composite structures are a significant source of hazardous air pollutant (HAP) emissions. One method of reducing styrene emissions from vinyl ester (VE) resins is to replace some or all of the styrene with fatty acid based monomers. This patented technology allows for the formulation of high-performance composite resins with no more than 25 weight-percent styrene, which is a 25% 50% reduction in HAP emissions vs. commercial VE resins. This work validated the commercially produced low-HAP vinyl ester resins from Applied Poleramics, Inc., for use in U.S. Department of Defense composite structures. Tests have shown that the established resin formulations met the property requirements, including viscosity, glass transition temperature, modulus, strength, short beam shear strength, fracture toughness, and weatherability. The Army has demonstrated and validated the use of the high-mobility multipurpose wheeled vehicle transmission container, M35A3 hood, and M939 hood under laboratory testing and field conditions. The Air Force has demonstrated the production of an F-22 canopy cover, T-38 dorsal cover, and rapid prototyping splash molds. Mine countermeasure rudders were successfully demonstrated at production level and validated at the laboratory level. An economic analysis has shown that these resins will cost an additional $0.1 $1.20/lb (depending on manufacturing scale) more than baseline resins. However, they reduce life cycle cost by more than $1.20/lb, making them economically feasible.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 2012
Accession Number
ADA562499

Entities

People

  • Caroline Lochner
  • Daniel De Bonis
  • Felecia Levine
  • James Sands
  • John J. La Scala
  • Kevin Andrews
  • Philip Myers
  • Robert Hayes
  • Steven Boyd
  • Terese Glodek

Organizations

  • United States Army Research Laboratory

Tags

Communities of Interest

  • Biomedical
  • Ground and Sea Platforms
  • Human Systems

DTIC Thesaurus Topics

  • Air Force
  • Air Force Facilities
  • Chemistry
  • Composite Materials
  • Fatty Acids
  • Glass Transition Temperature
  • Laminates
  • Manufacturing
  • Materials
  • Materials Laboratories
  • Materials Science
  • Materials Testing
  • Mechanical Working
  • Military Research
  • Organic Compounds
  • Transition Temperature
  • Volatile Organic Compounds

Readers

  • Internal Combustion Engine (ICE) Technology.
  • Logistics and Supply Chain Management.
  • Polymer Science and Engineering.