A Gas-Surface Interaction Model based on Accelerated Reactive Molecular Dynamics for Hypersonic Conditions including Thermal Conduction

Abstract

Vehicles traveling through an atmosphere at hypersonic speeds generate strong shock waves. These shock waves generate extremely high gas temperatures within the shock layer between the shock itself and the surface of the vehicle. As the gas reaches such high temperatures, its vibrational degrees of freedom become excited and diatomic and polyatomic molecules dissociate into reactive atomic species. At high altitudes characteristic of hypersonic flight where the free-stream density is low, these reactive species diffuse through the boundary layer and may chemically react with the vehicle s thermal protection system (TPS). Many TPS materials act as a catalyst for the heterogeneous recombination of dissociated species back into molecules. Such exothermic surface reactions transfer additional energy to the vehicle surface and thus contribute to the heat flux and overall heat load that the TPS must withstand. For example, studies have shown that surface catalysis can contribute up to 30% of the total heat load for Earth reentry [1].

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Document Details

Document Type
Technical Report
Publication Date
Feb 28, 2012
Accession Number
ADA567529

Entities

People

  • Ellad B. Tadmor
  • Ioana Cozmuta
  • Thomas E. Schwartzentruber

Organizations

  • University of Minnesota

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Boundary Layer
  • Ceramic Materials
  • Chemical Reactions
  • Chemistry
  • Computational Chemistry
  • Computational Fluid Dynamics
  • Density Functional Theory
  • Energy Transfer
  • Fluid Dynamics
  • Heat Transfer
  • Molecular Dynamics
  • Monte Carlo Method
  • Reaction Mechanisms
  • Recombination Reactions
  • Spacecraft
  • Surface Chemistry
  • Surface Reactions

Fields of Study

  • Physics

Readers

  • Aerospace Engineering.
  • Combustion science or combustion engineering.
  • Fluid Dynamics.

Technology Areas

  • Hypersonics
  • Hypersonics - Hypersonic Boundary Layers
  • Hypersonics - Hypersonic Flight