Electronically Excited States and Their Role in Affecting Thermodynamic and Transport Properties of Thermal Plasmas

Abstract

The contribution of internal degrees of freedom to thermal-plasma properties has been investigated in a wide range of temperature and pressure. Thermodynamic functions have been calculated modelling in different ways the electronic levels of atomic species (ground-state, Debye-Huckel and confined-atom approximations). Frozen and reactive specific heats are strongly affected by electronic excitation whereas compensation effects smooth its influence on the total specific heat, i.e. the sum of frozen and reactive contributions. High-order Chapman-Enskog method has been applied to evaluate transport coefficients. The inclusion of electronically excited states have a twofold impact, reflecting the changes on thermodynamic properties and on transport cross sections of excited species. Results for atomic hydrogen, nitrogen and air plasmas are considered in this lecture.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 2009
Accession Number
ADA567782

Entities

People

  • A. Laricchiuta
  • C. Catalfamo
  • D. Bruno
  • G. Colonna
  • M. Capitelli

Organizations

  • University of Bari

Tags

Communities of Interest

  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Boltzmann Equation
  • Chemistry
  • Coefficients
  • Collisions
  • Diffusion Coefficient
  • Electrical Conductivity
  • Electron Density
  • Energy Levels
  • Ground State
  • Ionization
  • Physical Chemistry
  • Physical Properties
  • Quantum Numbers
  • Specific Heat
  • Thermal Conductivity
  • Thermodynamic Properties
  • Transport Properties

Fields of Study

  • Physics

Readers

  • Calculus or Mathematical Analysis
  • Combustion science or combustion engineering.
  • Molecular Photonics/Laser Physics

Technology Areas

  • Microelectronics