Atomic Layer Deposition of Al2O3 on GaSb Using In Situ Hydrogen Plasma Exposure

Abstract

In this report, we study the effectiveness of hydrogen plasma surface treatments for improving the electrical properties of GaSb/Al2O3 interfaces. Prior to atomic layer deposition of an Al2O3 dielectric, p-GaSb surfaces were exposed to hydrogen plasmas in situ, with varying plasma powers, exposure times, and substrate temperatures. Good electrical interfaces, as indicated by capacitance-voltage measurements, were obtained using higher plasma powers, longer exposure times, and increasing substrate temperatures up to 250 deg C. X-ray photoelectron spectroscopy reveals that the most effective treatments result in decreased SbOx, decreased Sb, and increased GaOx content at the interface. This in situ hydrogen plasma surface preparation improves the semiconductor/insulator electrical interface without the use of wet chemical pretreatments and is a promising approach for enhancing the performance of Sb-based devices.

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Document Details

Document Type
Technical Report
Publication Date
Dec 03, 2012
Accession Number
ADA573732

Entities

People

  • Brian R. Bennett
  • Doewon Park
  • Erin R. Cleveland
  • J. B. Roos
  • James G. Champlain
  • Laura B Ruppalt
  • Sharka M. Prokes

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Capacitance
  • Capacitors
  • Carrier Mobility
  • Chemistry
  • Complementary Metal-Oxide Semiconductors
  • Compound Semiconductors
  • Dielectric Films
  • Dielectric Properties
  • Dielectrics
  • Electrical Properties
  • Electrons
  • Fermi Levels
  • Hydrogen
  • Measurement
  • Oxides
  • Semiconductors
  • X Ray Photoelectron Spectroscopy

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene