Portable SERS Instrument for Explosives Monitoring

Abstract

In this project, a new method based on surface-enhanced Raman spectroscopy (SERS) has been developed, fielded, and validated for field analysis of explosives in water samples. The SERS technique offers enhance performance over colorimetry and other field screening techniques for groundwater well, direct push and process water monitoring. When compared to the reference laboratory HPLC Method 8330 and field screening methods, the SERS method has the potential to reduce the time, cost, and waste generated per analysis while providing discriminate quantification of multiple analytes, even those within a chemical class, in a single measurement. This project entailed three demonstrations at two Army facilities Alabama Army Ammunition Plant (ALAAP) and Umatilla Chemical Depot (UMCD). The ALAAP demonstration was aimed at establishing that a SERS instrument could be brought from the laboratory to the field and used to perform explosives analysis on samples collected from groundwater wells. The purpose for the two demonstrations at UMCD was to extend the applicability of the SERS method from conventional groundwater well monitoring to include expedited site characterization from a cone penetrometer (CPT), direct push platform and at-line remediation process monitoring.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 2006
Accession Number
ADA603992

Entities

Organizations

  • Cold Regions Research and Engineering Laboratory

Tags

Communities of Interest

  • Biomedical
  • Counter IED
  • Human Systems

DTIC Thesaurus Topics

  • Analyzers
  • Chemical Analysis
  • Chemical Synthesis
  • Chemistry
  • Data Science
  • Detection
  • Detectors
  • Explosives
  • Groundwater
  • Information Science
  • Liquid Chromatography
  • Materials
  • Measurement
  • Monitoring
  • Raman Spectroscopy
  • Regression Analysis
  • Statistical Analysis

Readers

  • Computational Modeling and Simulation
  • Environmental Remediation and Restoration.
  • Groundwater Contamination Remediation.