Structural Analysis of the Dimerization Domain of the Human Estrogen Receptor and a Peptide Inhibitor of Dimerization

Abstract

The human estrogen receptor (hER) is a therapeutic target in estrogen-responsive breast cancers. It has been shown that a 12 amino acid phosphotyrosyl peptide composed of the sequence surrounding tyrosine 537 of hER is an inhibitor of the hER function. Base on a hypothesis that hER contains a discreet binding domain for the phosphopeptide, this project proposes to determine the three-dimensional structure of the proposed domain. Based on previous binding assay data, we prepared a fragment of hER corresponding to residues 253-341. Characterization using fluorescence and nuclear magnetic resonance spectroscopy, we show that this hER fragment does not have a well-defined structure, even in the presence of the phosphopeptide. These results, together with recently determined crystal structures of the hER ligand binding domain and other mutation studies, indicate that the original hypothesis is incorrect. Our new experiments suggest that the phosphopeptide inhibits hER by binding to the ligand binding domain. Thus, the focus of this project has been shifted to identifying the binding site within the hER ligand binding domain and identifying critical interactions. Results from this project will provide insights into development of new hER inhibitors for treatment of estrogen-responsive breast cancers.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1998
Accession Number
ADB241545

Entities

People

  • Shohei Koide

Organizations

  • University of Rochester

Tags

DTIC Thesaurus Topics

  • Amino Acids
  • Biomedical Research
  • Breast Cancer
  • Chemistry
  • Crystal Structure
  • Estrogens
  • Hormones
  • Inhibitors
  • Magnetic Resonance
  • Neoplasms
  • Nuclear Magnetic Resonance
  • Peptides
  • Physical Properties
  • Resonance
  • Spectroscopy
  • Three Dimensional
  • Tyrosine

Fields of Study

  • Chemistry

Readers

  • Molecular and Cellular Biochemistry