Superoleophobic Textiles

Abstract

A superoleophobic surface has been achieved by modeling surface morphology and reducing surface energy. A meta-stable Cassie-Baxter model, which describes the transition from a Cassie-Baxter surface to a Wenzel surface caused by the local minimization of surface free energy due to air pockets inside the rough structure, has been used to account for the superoleophobic effect. Under the guidance of AFRL, Natick Soldier RD&EC, and Defense Science and Technology Laboratory (Dstl), we have explored three different techniques to achieve superhydrophobicity and superoleophobicity using nylon/cotton woven fabric (nyco) and hydroentangled nylon nonwoven fabric: pulsed plasma polymerization of fluorodecyl acrylate (PFAC8), microwave-assisted condensation of perfluorodecyltrimethoxysilane (FS), and FS condensation through wet processing. Fabric materials prepared using these three techniques were superhydrophobic and superoleophobic as shown by their very high contact angles for both water and oils. The measured contact angles agree with the predicted values obtained through designing a Cassie-Baxter surface.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 2011
Accession Number
ADB374970

Entities

People

  • Colin Willis
  • Corinne Stone
  • Duyanada Satan
  • Euigyoung Jeong
  • Hoon Joo Lee
  • Jimmei Du
  • Rahul Saraf
  • Stephen Michielsen

Organizations

  • North Carolina State University

Tags

Communities of Interest

  • Advanced Electronics
  • Biomedical

DTIC Thesaurus Topics

  • Air Force
  • Air Force Research Laboratories
  • Chemical Synthesis
  • Chemistry
  • Electron Microscopes
  • Electron Microscopy
  • Hydrophilic Properties
  • Hydrophobic Properties
  • Hydroxides
  • Materials
  • Materials Science
  • Measurement
  • Oleophobic Properties
  • Surface Energy
  • Surface Roughness
  • Surface Tension
  • United States

Fields of Study

  • Chemistry

Readers

  • Pulsed Power and Plasma Physics.
  • Reinforced Composite Materials
  • Surface Coatings Technology.