Evidence for Antiferroelectric Behavior in KNbO3/KTaO3 Superlattices

Abstract

The dielectric response in artificially layered 1x1 KTaO3/KNbO3 perovskite superlattice structures is reported. While KTaO3 and KNbO3 are ferroelectric or paraelectric, respectively, superlattices appear antiferroelectric based on an increase in dielectric constant with applied dc bias. This "positive tunability" in dielectric response occurs at the same temperature region where a structural phase transition is observed. This dielectric behavior is inconsistent with the nonlinear response for either paraelectric or ferroelectric materials. However, an increase in the dielectric constant with applied electric field is consistent with antiferroelectric behavior. The antiferroelectric ordering correlates with cation modulation imposed by the superlattice.

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Document Details

Document Type
Technical Report
Publication Date
Apr 03, 2003
Accession Number
ADP013366

Entities

People

  • D. P. Norton
  • H. M. Christen
  • John B. Sigman
  • L. A. Boatner
  • P. H. Fleming

Organizations

  • University of Florida

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Capacitance
  • Chemical Compounds
  • Dielectric Permittivity
  • Dielectric Properties
  • Dielectrics
  • Diffraction
  • Electric Fields
  • Engineered Materials
  • Films
  • Free Energy
  • Materials
  • Materials Science
  • Phase Transformations
  • Solid Solutions
  • Transition Temperature
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
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